GoCentral is GoDaddy's DIY website builder system vs WordPress (I assume you mean the Managed WordPress offering) is a full WordPress website where GoDaddy manages the backend server / settings so you don't have to
It really depends on what your needs are for your site and what you are looking to do
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Re: What is the Difference in using GoDaddy GoCentral Buisness and GoDaddy WordPress?
These are different style website management tools. It depends on the needs of your website and personal preferences to what would be a better fit. GoCentral is streamlined to quickly and easily build a basic website, but it's not very flexible. WordPress is much more customizable, but with that comes added effort to setup and manage.