Unfortunately, that is too comprehensive for the current appointments application as it is based on your settings timezone and established business hours. Web builders, as great as they are, do have some limitations. 😉
Options: There are 3rd party services you can link to/embed and/or WordPress has a bunch of plugins that offer onsite comprehensive scheduling functionality.
Judith "Many of life's failures are people who did not realize how close they were to success when they gave up." ~Thomas Edison