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PHP error log is empty

I have php_error.log file in my webroot. However, it is always empty even though I am getting Service unavailable error when I am trying to some some tasks. Godaddy instructions say:

Place the following line in your initialization file:
error_log = /path/to/your/webroot/php_error.log

What exactly does /path/to/your/webroot/ mean? Is it full url of my site (like

error_log = ) or is it something else? If it is full url of my site, should it be preceded by forward slash like is their instructions?